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Mark R. Antonio

Mark R. Antonio (Michigan State University)
is a Chemist. His activities are centered on
molecular and surface spectroscopic techniques,
especially synchrotron, X-Ray absorption
fine structure, and Mössbauer-effect
spectroscopy, for the characterization of
substances containing heavy metals.  

Address

Building 200 - M155
Chemistry Division
Argonne National Laboratory
Argonne, IL 60439, U.S.A
Phone: 630/252-9267
Fax: 630/252-4225
E-Mail : mantonio@anl.gov

Publications

X-ray absorption spectroscopy of the actinides
M. R. Antonio and L. Soderholm
In The Chemistry of the Actinide and Transactinide Elements,
3rd Ed., L. R. Morss, N. Edelstein, J. Fuger, and J. J. Katz, Eds.,
Springer, 2006, Vol. 5, Chapter 28, pp. 3086-3198

Actinyl peroxide nanospheres
P. C. Burns, K.-A. H. Kubatko, G. Sigmon, B. J. Fryer, J. Gagnon,
M. R. Antonio, and L. Soderholm
Angew. Chem., Int. Ed. 44 (14), 2135-2139 (2005)

Redox chemistry of the Keggin heteropolyoxotungstate anion in
ionic liquids
M-H. Chiang, J. A. Dzielawa, M. L. Dietz, and M. R. Antonio
J. Electroanalytical Chem. 567 (1), 77-84 (2004)

A unique coordination environment for an ion: EXAFS studies and
bond valence model approach of the encapsulated cation in the
Preyssler anion
M-H. Chiang, M. R. Antonio, C. W. Williams, and L. Soderholm
Dalton Trans. 5, 801-806 (2004)

Redox chemistry of actinide ions in Wells-Dawson heteropolyoxoanion
complexes
M-H. Chiang, L. Soderholm, and M. R. Antonio
Eur. J. Inorg. Chem. 2003 (16), 2929-2936 (2003)

Cover Picture: Redox chemistry of actinide ions in Wells-Dawson
heteropolyoxoanion complexes
M-H. Chiang, L. Soderholm, and M. R. Antonio
Eur. J. Inorg. Chem. 2003 (16), (2003)

Coordination of actinide ions in Wells-Dawson heteropolyoxoanion complexes
M-H. Chiang, C. W. Williams, L. Soderholm, and M. R. Antonio
Eur. J. Inorg. Chem. 14, 2663-2669 (2003)

Berkelium redox speciation
M. R. Antonio, C. W. Williams, and L. Soderholm
Radiochim. Acta 90, 851-856 (2002)

Correlated electrons in the Eu-exchanged Preyssler anion [EuP5W30O110]n-
L. Soderholm, M. R. Antonio, S. Skanthakumar, and C. W. Williams
J. Am. Chem. Soc. 124 (25), 7290-7291 (2002)

Coordination of rare-earth elements in complexes with monovacant
Wells-Dawson polyoxoanions
Q-H. Luo, R. C. Howell, M. Dankova, J. Bartis, C. W. Williams,
W. DeW. Horrocks, Jr., V. G. Young, Jr., A. L. Rheingold,
L. C. Francesconi, and M. R. Antonio
Inorg. Chem. 40, 1894-1901 (2001)

The coordination geometry of Np(VII) in alkaline solution
C. W. Williams, J.-P. Blaudeau, J. C. Sullivan, M. R. Antonio,
B. Bursten, and L. Soderholm
J. Am. Chem. Soc. 123, 4346-4347 (2001)

Neptunium redox speciation
M. R. Antonio, L. Soderholm, C. W. Williams, J. P. Blaudeau, and B. E. Bursten
Radiochim. Acta 89 (1), 17-25 (2001)

Probing redox reactions at a synchrotron: The coordination geometry of Np(VII)
C. W. Williams, J. C. Sullivan, M. R. Antonio, and L. Soderholm
APS Forefront 1, 152-154 (2001)

Formation of UO2(BO3)4 Clusters in B2O3 Glass due to Charge
Transfer and Vibronic Effects
G. K. Liu, V. S. Vikhnin, H. Z. Zhuang, K. S. Hong, J. V. Beitz,
M. R. Antonio, L. Soderholm, and C. W. Williams
J. Luminescence 94-95, 677-681 (2001)

X-ray excited optical luminescence (XEOL) as a detection scheme
for characterizing materials
L. Soderholm, G. K. Liu, M. R. Antonio, and M. F. Reid
Encyclopedia of Materials: Science and Technology 2001,
Elsevier Science Ltd., pp. 1140-1142 (2001)

The formation and stability of [EuP5W30O110]12- and [AmP5W30O110]12-
C. W. Williams, M. R. Antonio, and L. Soderholm
J. Alloys Compd. 303-304, 509-513 (2000)

In situ Co K-edge X-ray absorption fine structure of cobalt hydroxide film
electrodes in alkaline solutions
D. Totir, Y. Mo, S. Kim, M. R. Antonio, and D. A. Scherson
J. Electrochem. Soc. 147 (12), 4594-4597 (2000)

Utilization of principal component analysis on plutonium EXAFS data from
the advanced photon source
J. Terry, R. K. Schulze, T. G. Zocco, J. D. Farr, J. Archuleta, M. Ramos,
R. Martinez, B. Martinez, R. Pereyra, J. Lashley, S. Wasserman, M. Antonio,
S. Skanthakumar, and L. Soderholm
AIP Conf. Proc. 532 (Plutonium Futures--The Science), 364-366 (2000)

The influence of Desulfovibrio desulfuricans on neptunium chemistry
L. Soderholm, C. W. Williams, M. R. Antonio, M. L. Tischler, and M. Markos
Mater. Res. Soc. Symp. Proc. 590 (Applications of Synchrotron Radiation
Techniques to Materials Science V), 27-32 (2000)

In-situ Ru K-edge x-ray absorption fine structure studies of electroprecipitated
ruthenium dioxide films with relevance to supercapacitor applications
Y. Mo, M. R. Antonio, and D. A. Scherson
J. Phys. Chem. B 104 (42), 9777-9779 (2000)

Studies of local structure of Cm3+ in borosilicate glass using laser and x-ray
spectroscopic methods and computational modeling
G. K. Liu, V. V. Zhorin, M. R. Antonio, S. T. Li, C. W. Williams, and
L. Soderholm
J. Chem. Phys. 112 (3), 1489-1496 (2000)

Iron chemistry in petroleum production
M. R. Antonio, G. B. Karet, and J. P. Guzowski, Jr.
Fuel 79 (1), 37-45 (2000)

Extracellular iron-sulfur precipitates from growth of Desulfovibrio desulfuricans
M. R. Antonio, M. L. Tischler, and D. Witzcak
Mater. Res. Soc. Symp. Proc. 590 (Applications of Synchrotron Radiation
Techniques to Materials Science V), 33-38 (2000)

XANES Spectroelectrochemistry: A New Method for Determining
Formal Potentials
L. Soderholm, M. R. Antonio, C. Williams, and S. R. Wasserman
Anal. Chem. 71 (20), 4622-4628 (1999)

Redox behavior of cerium in heteropolyoxotungstate complexes
M. R. Antonio, L. Soderholm, C. W. Williams, N. Ullah, and
L. C. Francesconi
J. Chem. Soc., Dalton Trans. (21), 3825-3830 (1999)

Tetravalent uranium in calcite
N. C. Sturchio, M. R. Antonio, L. Soderholm, S. R. Sutton, and J. C. Brannon
Science (Washington, D. C.) 281 (5379), 971-973 (1998)

X-ray excited optical luminescence (XEOL) detection of x-ray absorption fine
structure (XAFS)
L. Soderholm, G. K. Liu, M. R. Antonio, and F. W. Lytle
J. Chem. Phys. 109 (16), 6745-6752 (1998)

Synthesis and characterization of actinide-exchanged Preyssler
heteropolyanions [AnP5W30O110]n- (An = Th, Am, Cm)
M. R. Antonio, C. W. Williams, and L. Soderholm
J. Alloys Compd. 271-273, 846-849 (1998)

Coordination and valence of europium in [Eu(a-2-As2W17O61)2]17- and
[Eu(W5O18)2]9-
M. R. Antonio, L. Soderholm, G. Jennings, L. C. Francesconi, M. Dankova,
and J. Bartis
J. Alloys Compd. 275-277, 827-830 (1998)

In Situ Fe K-Edge x-ray absorption fine structure of a pyrite electrode in a
Li/Polyethylene oxide(LiClO4)/FeS2 battery environment
D. A. Totir, I. T. Bae, Y. Hu, M. R. Antonio, M. A. Stan, and
D. A. Scherson
J. Phys. Chem. B 101 (47), 9751-9756 (1997)

Oxidation state of the unusual rare earth (R = Ce, Pr and Tb) in double-layer
high-Tc superconductors
U. Staub, L. Soderholm, S. Skanthakumar, and M. R. Antonio
J. Phys. IV 7 (C2, X-Ray Absorption Fine Structure, Vol. 2), 1077-1079
(1997)

The effect of f-ion valence on superconductivity in the series Pb2Sr2RCu3O8
(R = Ce, Pr, Tb and Am)
L. Soderholm, S. Skanthakumar, U. Staub, M. R. Antonio, and C. W. Williams
J. Alloys Compd. 250 (1-2), 623-626 (1997)

In situ x-ray absorption fine structure studies of a manganese dioxide electrode
in a rechargeable MnO2/Zn alkaline battery environment
Y. Mo, Y. Hu, I. T. Bae, B. Miller, M. R. Antonio, and D. A. Scherson
J. Electrochem. Soc. 144 (5), 1598-1603 (1997)

In situ x-ray absorption fine structure and optical reflectance studies of
electrodeposited nickel hydrous oxide films in alkaline electrolytes
Y. Hu, I. T. Bae, Y. Mo, M. R. Antonio, and D. A. Scherson
Can. J. Chem. 75 (11), 1721-1729 (1997)

EXAFS studies of cesium complexation by dibenzo-crown ethers in tri-n-butyl
phosphate
M. R. Antonio, M. L. Dietz, M. P. Jensen, L. Soderholm, and E. P. Horwitz
Inorg. Chim. Acta 255 (1), 13-20 (1997)

Local environments of erbium and lutetium in sodium silicate glasses
M. R. Antonio, L. Soderholm, and A. J. G. Ellison
J. Alloys Compd. 250 (1-2), 536-540 (1997)

Implications of the unusual redox behavior exhibited by the heteropolyanion
[EuP5W30O110]12-
M. R. Antonio and L. Soderholm
J. Alloys Compd. 250 (1-2), 541-543 (1997)

Design of spectroelectrochemical cell for in-situ x-ray absorption fine structure
measurements of bulk solution species
M. R. Antonio, L. Soderholm, and I. Song
J. Appl. Electrochem. 27 (7), 784-792 (1997)

The synthesis and characterization of the superconductor-related compound
Pb2Sr2AmCu3O8
L. Soderholm, C. Williams, S. Skanthakumar, M. R. Antonio, and
S. Conradson
Z. Phys. B: Condens. Matter 101 (4), 539-545 (1996)

In situ vanadium K-edge and tungsten LIII-edge x-ray absorption fine
structure of vanadium-substituted heteropolytungstates immobilized in a
high-area carbon electrode in acid aqueous electrolytes
D. E. Clinton, D. A. Tryk, I. T. Bae, F. L. Urbach, M. R. Antonio, and
D. A. Scherson
J. Phys. Chem. 100 (47), 18511-18514 (1996)

Comparison of the cation valences and coordinations in Ce2UO6 and
Ce2MoO6
M. R. Antonio, U. Staub, J. S. Xue, and L. Soderholm
Chem. Mater. 8 (11), 2673-2680 (1996)

Redox behavior of europium in the Preyssler heteropolyanion
[EuP5W30O110]12-
M. R. Antonio and L. Soderholm
J. Cluster Sci. 7 (4), 585-591 (1996)

Polymorphs of Ln2MoO6: A neutron diffraction investigation of the crystal
structures of La2MoO6 and Tb2MoO6
J. S. Xue, M. R. Antonio, and L. Soderholm
Chem. Mater. 7 (2), 333-40 (1995)

Electrochemical insertion of lithium into pyrite from nonaqueous electrolytes
at room temperature: An in situ Fe K-edge x-ray absorption fine structure study
D. A. Tryk, S. Kim, Y. Hu, W. Xing, D. A. Scherson, M. R. Antonio,
V. Z. Leger, and G. E. Blomgren
J. Phys. Chem. 99 (11), 3732-5 (1995)

In situ x-ray absorption fine structure measurements of LaNi5 electrodes in
alkaline electrolytes
D. A. Tryk, I. T. Bae, Y. Hu, S. Kim, M. R. Antonio, and D. A. Scherson
J. Electrochem. Soc. 142 (3), 824-8 (1995)

In situ La, Ce, and Nd L-edge x-ray absorption fine structure study of an
intermetallic metal hydride electrode in an operating alkaline battery
D. A. Tryk, I. T. Bae, D. Scherson, M. R. Antonio, G. W. Jordan, and
E. L. Huston
J. Electrochem. Soc. 142 (5), L76-L78 (1995)

Oxidation state and magnetic properties of Pb2Sr2Tb1-xYxCu3O8
U. Staub, L. Soderholm, S. Skanthakumar, and M. R. Antonio
Phys. Rev. B: Condens. Matter 52 (13), 9736-45 (1995)

In situ total-electron-yield sulfur K-edge XAFS measurements during exposure
of copper to an SO2-containing humid atmosphere
I. Song, B. Rickett, P. Janavicius, J. H. Payer, and M. R. Antonio
Nucl. Instrum. Methods Phys. Res., Sect. A 360 (3), 634-41 (1995)

An iron K-edge XANES study of iron and iron oxides for the cathodic
disbonding of fusion bonded epoxy in alkaline aqueous solution
I. Song, M. R. Antonio, and J. H. Payer
J. Electrochem. Soc. 142 (7), 2219-24 (1995)

Coordination and Valence of Europium in the Heteropolyanion
[EuP5W30O110]12-
L. Soderholm, G. K. Liu, J. Muntean, J. Malinsky, and M. R. Antonio
J. Phys. Chem. 99 (23), 9611-16 (1995)

The oxidation state and magnetic behavior of Tb in high-Tc related materials
L. Soderholm, U. Staub, S. Skanthakumar, and M. R. Antonio
Mater. Res. Soc. Symp. Proc. 376 (Neutron Scattering in Materials Science II),
529-34 (1995)

In situ extended x-ray absorption fine structure of an iron porphyrin
irreversibly adsorbed on an electrode surface
S. Kim, D. Tryk, I. T. Bae, M. Sandifer, R. Carr, M. R. Antonio, and
D. A. Scherson
J. Phys. Chem. 99 (25), 10359-64 (1995)

Synthesis and properties of lanthanide-exchanged Preyssler's
heteropolyanions
M. R. Antonio, J. Malinsky, and L. Soderholm
Mater. Res. Soc. Symp. Proc. 368 (Synthesis and Properties of Advanced
Catalytic Materials), 223-8 (1995)

The electronic properties of Ce in CeFe4P12
S. J. Xue, M. R. Antonio, W. T. White, L. Soderholm, and S. M. Kauzlarich
J. Alloys Compd. 207-208, 161-4 (1994)

Tb oxidation state and hybridization in Y0.9Tb0.1Ba2Cu3O7-d (d = 0.02, 0.84):
a magnetic-susceptibility and x-ray-absorption study
U. Staub, M. R. Antonio, L. Soderholm, M. Guillaume, W. Henggeler,
and A. Furrer
Phys. Rev. B: Condens. Matter 50 (10), 7085-91 (1994)

The application of x-ray absorption spectroscopy to the analysis of tarnish
products formed in mixed flowing gas environments
B. I. Rickett, I. Song, P. Janavicius, M. R. Antonio, and J. H. Payer
Proc. - Electrochem. Soc. 94-29 (Corrosion and Reliability of Electronic
Materials and Devices), 26-37 (1994)

In situ x-ray absorption fine structure studies of foreign metal ions in nickel
hydrous oxide electrodes in alkaline electrolytes
S. Kim, D. A. Tryk, M. R. Antonio, R. Carr, and D. Scherson
J. Phys. Chem. 98 (40), 10269-76 (1994)

The oxidation state of cerium in Ce2MoO6
M. R. Antonio, J. S. Xue, and L. Soderholm
J. Alloys Compd. 207-208, 444-8 (1994)

Cerium valence in cerium-exchanged Preyssler's heteropolyanion through
x-ray absorption near-edge structure
M. R. Antonio and L. Soderholm
Inorg. Chem. 33 (26), 5988-93 (1994)

Synthesis, structure and characterization of Ce1-xAxTiO3 (0.0 < x < 0.8;
A = strontium, barium)
J. E. Sunstrom, S. M. Kauzlarich, and M. R. Antonio
Chem. Mater. 5 (2), 182-91 (1993)

Applications of x-ray absorption fine structure to the in situ study of the
effect of cobalt in nickel hydrous oxide electrodes for fuel cells and
rechargeable batteries
S. Kim, D. A. Tryk, M. R. Antonio, and D. Scherson
Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem. 38 (4), 1457-63 (1993)

Silver ion coordination in membranes for facilitated olefin transport
M. R. Antonio and D. T. Tsou
Ind. Eng. Chem. Res. 32 (2), 273-8 (1993)

The oxidation state and coordination environment of chromium in a sealed
anodic aluminum oxide film by x-ray absorption spectroscopy
J. S. Wainright, O. J. Murphy, and M. R. Antonio
Corros. Sci. 33 (2), 281-93 (1992)

Extended X-ray Absorption Fine Structure
M. R. Antonio
In Encyclopedia of Materials Characterization: Surfaces, Interfaces, Thin
Films
, edited by C. R. Brundle, C. A. Evans, Jr and S. Wilson (Butterworth-
Heinemann, Boston, 1992), pp. 214-226

In situ XANES of an iron porphyrin irreversibly adsorbed on an electrode
surface
S. Kim, I. T. Bae, M. Sandifer, P. N. Ross, R. Carr, J. Woicik, M. R. Antonio,
and D. A. Scherson
J. Am. Chem. Soc. 113 (24), 9063-6 (1991)

Coordination and valence of niobium in titanium dioxide-niobium dioxide
solid solutions through x-ray absorption spectroscopy
M. R. Antonio, I. Song, and H. Yamada
J. Solid State Chem. 93 (1), 183-92 (1991)

The chemistry of the thermal decomposition of pseudobrookite ferrous
titanium oxides
R. G. Teller, M. R. Antonio, A. E. Grau, M. Gueguin, and E. Kostiner
J. Solid State Chem. 88 (2), 351-67 (1990)

Structural analysis of metastable pseudobrookite ferrous titanium oxides with
neutron diffraction and Mössbauer spectroscopy
R. G. Teller, M. R. Antonio, A. E. Grau, M. Gueguin, and E. Kostiner
J. Solid State Chem. 88 (2), 334-50 (1990)

Structural environments and oxidation states of metal cations in bismuth
cerium molybdate solid solutions by x-ray absorption spectroscopy
M. R. Antonio, J. F. Brazdil, L. C. Glaeser, M. Mehicic, and R. G. Teller
J. Phys. Chem. 92 (8), 2338-45 (1988)

Structural characterization of bismuth molybdates by x-ray absorption
spectroscopy and powder neutron diffraction profile analysis
M. R. Antonio, R. G. Teller, D. R. Sandstrom, M. Mehicic, and J. F. Brazdil
J. Phys. Chem. 92 (10), 2939-44 (1988)

Interlayer coordination environments of iron, cobalt, and nickel in vanadyl
phosphate dihydrate, VOPO4•2H2O, intercalation compounds
M. R. Antonio, R. L. Barbour, and P. R. Blum
Inorg. Chem. 26 (8), 1235-43 (1987)

New materials synthesis: characterization of some metal-doped antimony
oxides
R. G. Teller, M. R. Antonio, J. F. Brazdil, and R. K. Grasselli
J. Solid State Chem. 64 (3), 249-60 (1986)

Stabilization of high-temperature antimony oxide with molybdenum
incorporation. Structure of molybdenum-doped antimony oxide (Sb2O4)
by powder neutron diffraction and extended x-ray absorption fine structure
spectroscopy
R. G. Teller, M. R. Antonio, J. F. Brazdil, M. Mehicic, and R. K. Grasselli
Inorg. Chem. 24 (21), 3370-5 (1985)

Tungsten as a weak backscatter: an example of information loss in extended
x-ray absorption fine structure (EXAFS) spectroscopy. Tungsten and iron
EXAFS studies of tungsten-iron-sulfur clusters containing the WS2Fe unit
M. R. Antonio, B. K. Teo, and B. A. Averill
J. Am. Chem. Soc. 107 (12), 3583-90 (1985)

Molybdenum K-edge extended x-ray absorption fine structure studies
of synthetic molybdenum-iron-sulfur clusters containing the MoS4 unit:
development of a fine adjustment technique based on models
B. K. Teo, M. R. Antonio, and B. A. Averill
J. Am. Chem. Soc. 105 (12), 3751-62 (1983)

EXAFS model for the iron-molybdenum cofactor of nitrogenase:
molybdenum, tungsten, and iron EXAFS of the [Cl2FeS2MS2FeCl2]2-
(M = molybdenum or tungsten) dianions. A comparison with the Mo
EXAFS of nitrogenase
B. K. Teo, M. R. Antonio, D. Coucouvanis, E. D. Simhon, and P. P. Stremple
J. Am. Chem. Soc. 105 (18), 5767-70 (1983)

EXAFS of glassy metallic alloys: amorphous and crystalline
molybdenum-nickel (MoNi)
B. K. Teo, H. S. Chen, R. Wang, and M. R. Antonio
J. Non-Cryst. Solids 58 (2-3), 249-74 (1983)

Intercalation of tetrathiafulvalene, tetrathiatetracene, and related molecules
into iron oxychloride
B. A. Averill, S. M. Kauzlarich, and M. R. Antonio
J. Phys., Colloq. (C3, Colloq. Int. CNRS Phys. Chim. Met. Synth. Org., 1982),
1373-6 (1983)

Iron and molybdenum extended x-ray absorption fine structure studies of
double-cubane clusters containing molybdenum iron sulfide (MoFe3S4) cores
M. R. Antonio, B. K. Teo, W. E. Cleland, and B. A. Averill
J. Am. Chem. Soc. 105 (11), 3477-84 (1983)

New EXAFS models for the iron sites of the iron-molybdenum cofactor in
nitrogenase: the [(p-CH3C6H4S)2FeS2FeS2MoS2]3- trianion and the
[(C6H5O)2FeS2MoS2]2- dianion
B. K. Teo, M. R. Antonio, R. H. Tieckelmann, H. C. Silvis, and B. A. Averill
J. Am. Chem. Soc. 104 (22), 6126-9 (1982)

Core dimensions in the 3Fe cluster of Desulfovibrio gigas ferredoxin II by
extended x-ray absorption fine structure spectroscopy
M. R. Antonio, B. A. Averill, I. Moura, J. J. G. Moura, W. H. Orme-Johnson,
B. K. Teo, and A. V. Xavier
J. Biol. Chem. 257 (12), 6646-9 (1982)

Iron EXAFS of the iron-molybdenum cofactor of nitrogenase
M. R. Antonio, B. K. Teo, W. H. Orme-Johnson, M. J. Nelson, S. E. Groh,
P. A. Lindahl, S. M. Kauzlarich, and B. A. Averill
J. Am. Chem. Soc. 104 (17), 4703-5 (1982)

Intercalation of tetrathiafulvalene into iron oxychloride
M. R. Antonio and B. A. Averill
J. Chem. Soc., Chem. Commun. (8), 382-3 (1981)

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